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Base catalyzed rearrangement of oxy-cope systems |
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| Authors: | R. Uma S. Swaminathan K. Rajagopalan |
| Affiliation: | Department of Organic Chemistry University of Madras, Guindy Campus Madras - 600 025, India |
| Abstract: | The synthesis and rearrangement of the optically active etynyl and vinyl carbinols 3 and 4 are reported. The rearrangements are found to be concerted when carried out with KH-THF and non-concerted with KOH-methanol. |
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