The enantiospecific synthesis of (4S,5R)-and (4S,5S)-4,5-dihydroxydecanoic acid γ-lactones,proposed autoregulators from |
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Authors: | Roderick D Cooper Veerappa B Jigajinni Richard H Wightman |
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Institution: | Department of Chemistry, Heriot-Watt University, Riccarton, Edinburgh, EH14 4AS, Scotland. |
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Abstract: | Both the (4S,5R)- and (4S,5S)-isomers of 4,5-dihydroxydecanoic acid γ-lactone, natural products and proposed autoregulators of Streptomyces Griseus, have been synthesised directly and in high yield from D-ribose via a common intermediate. |
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