Stereochemical requirements for fragmentation of homoallylic epoxy alcohols |
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| Authors: | Robert A. Holton Robert M. Kennedy |
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| Affiliation: | Department of Chemistry Virginia Polytechnic Institute and State University Blacksburg, Virginia 24061 U.S.A. |
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| Abstract: | The fragmentation of 5,6-epoxynorbornan-2-ol and 5,6-epoxynorbornan-2-one have been studied under both acidic and basic conditions. These processes show a clear preference for syn periplanar alignment of breaking bonds. |
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