Electrooxidative simulation of stereoselectivity in microsomal allylic hydroxylation |
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| Authors: | Tatsuya Shono Toshiki Toda Nozomu Oshino |
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| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Sakyo, Kyoto 606, Japan;Research II, Nihon Schering K.K., 2-6-64, Nishimiyahara Yodogawa, Osaka 532, Japan |
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| Abstract: | A comparison of the stereochemistry of liver microsomal γ-hydroxylation of some cyclic α, β-unsaturated ketones with that of electrochemical γ-acetoxylation of the corresponding dienol esters and with that of peracid oxidation of the dienol esters has been carried out. |
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