An efficient synthesis of isocarbacyclin starting from furfural |
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| Authors: | Toshiaki Mase Mikiko Sodeoka Masakatsu Shibasaki |
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| Affiliation: | Sagami Chemical Research Center, Nishi-Ohnuma, Sagamihara 229, Japan |
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| Abstract: | Two synthetic routes to isocarbacyclin starting from furfural are described. One route involves the regioselective hydrogenation of the disubstituted olefin in the presence of two other olefinic double bonds, and the other includes the highly regioselective organocopper coupling with the allylic etectrophile as a key step. |
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