Allergenic α-methylene-γ-lactones. A simple method for the introduction of deuterium in sesquiterpenic α-methylene-γ-butyrolactones. |
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| Authors: | Jean-Luc Stampf Claude Benezra |
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| Institution: | Laboratoire de Dermato-Chimie, Associé au CNRS (LA 31), Universite Louis Pasteur,Clinique Dermatologique, CHU de Strasbourg,67091 Strasbourg, France. |
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| Abstract: | Sodium borohydride reduction of sesquiterpene lactone vinylic sulfoxides in a deuterated solvent lead to 2H-Iabeled natural allergens ; the mechanism of hydride addition is discussed. |
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