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Allergenic α-methylene-γ-lactones. A simple method for the introduction of deuterium in sesquiterpenic α-methylene-γ-butyrolactones.
Authors:Jean-Luc Stampf  Claude Benezra
Institution:Laboratoire de Dermato-Chimie, Associé au CNRS (LA 31), Universite Louis Pasteur,Clinique Dermatologique, CHU de Strasbourg,67091 Strasbourg, France.
Abstract:Sodium borohydride reduction of sesquiterpene lactone vinylic sulfoxides in a deuterated solvent lead to 2H-Iabeled natural allergens ; the mechanism of hydride addition is discussed.
Keywords:
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