Über verbesserte Ru(II)-hydrierungskatalysatoren mit dreizähnigen cyclopentadienyldiphosphan-liganden (1) |
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Authors: | Thomas Kauffmann Jürgen Olbrich |
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Institution: | Organisch-Chemisches Institut der Universität Münster, Orléans-Ring 23, D-4400 Münster, West-Germany |
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Abstract: | The novel complexes 4a and b have been synthesized by complexation of Ru(II) with the tridentate ligands Ph2P-(CH2)n-P(Ph)-(CH2)2-Cp (n = 3,4). 4b, compared with other Ru(II) phosphane complexes, showed superior capacity as hydrogenation catalyst. |
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