Palladium(O) and rhodium(I) catalysis of the carbonylation of unactivated bromides |
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| Authors: | Khaled E Hashem James B Woell Howard Alper |
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| Institution: | Ottawa-Carleton Institute for Research and Graduate Studies in Chemistry, Department of Chemistry, University of Ottawa, Ottawa, Ontario Canada K1N 9B4 |
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| Abstract: | Alkyl, vinyl, and aromatic bromides react with organoborates and carbon monoxide, in the presence of catalytic quantities of 1,5-hexadienerhodium(I) chloride dimer and tetrakis(triphenylphosphine)palladium(O),to give carboxylic esters in good yields. |
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