Carbanion-accelerated Claisen rearrangements 3. Vicinal quaternary centers |
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| Authors: | Scott E Denmark Michael A Harmata |
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| Institution: | Roger Adams Laboratory, School of Chemical Sciences, University of Illinois, Urbana, Illinois 61801 U.S.A. |
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| Abstract: | The preparation and Claisen rearrangement of highly substituted allyl vinyl ethers is described. It is demonstrated that the thermal and anionic versions of the Claisen rearrangement are capable of creating vicinal quaternary centers. |
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