Hydroformylation as a simple and efficient one carbon homologation of homoallylic alcohols. Synthesis of prelog-djerassi lactone. |
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Authors: | PGM Wuts ML Obrzut PA Thompson |
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Institution: | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 U.S.A. |
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Abstract: | A hydroformylation oxidation sequence is described for the efficient conversion of homoallylic alcohols to δ-lactones. The methodology is applied to the synthesis of Prelog-Djerassi lactone. |
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