Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanol |
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| Authors: | Hideo Tomioka Norihiro Hayashi Yasuji Izawa Michael TH Liu |
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| Institution: | 1. Department of Industrial Chemistry, Faculty of Engineering, Mie University, Tsu, Mie 514 Japan;2. Department of Chemistry, University of Prince Edward Island, Charlottetown, Prince Edward Island, Canada, C1A 4P3 |
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| Abstract: | Benzylchlorocarbenes generated photolytically from diazirines in EtOH afford chlorostyrenes and acetals, whose distributions are sensitive to the reaction temperature. |
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