Stereoselective synthesis of trans-hydrindanes by internal vinylsilane acylation |
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| Authors: | Kentaro Fukuzaki Eiichi Nakamura Isao Kuwajima |
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| Affiliation: | Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo 152, Japan |
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| Abstract: | -Hydrindanediones (1, 3, and 15) have been synthesized in short steps through stereoselective introduction of vinylsilane units onto the cycloalkenones 5 or 10 followed by AgBF4-mediated internal acylation of the vinylsilane moiety. |
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