Allylic alkylations catalyzed by the couple palladium complexes-alumina |
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| Authors: | D. Ferroud J.P. Genet J. Muzart |
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| Affiliation: | 1. Laboratoire de Synthése organique et organomitallique, Laboratoire associé au C.N.R.S., Université Pierre et Marie Curie, 75005 Paris France;2. Laboratoire de Photochimie, Unité de Recherche associée au CNRS, Université de Champagne-Ardenne, Moulin de La Housee, 51062 Reims France. |
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| Abstract: | Using both palladium complexes and alumina, nucleophilic substitution of allyl acetate by various nucleophiles (pKa = 5–13) are realized with good yields at room temperature without preformation of the corresponding carbanions. |
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