Some new aspects of conjugate addition of grignard and alkyllithium reagents to vinylsilanes |
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| Authors: | Kohei Tamao Ryuichiro Kanatani Makoto Kumada |
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| Affiliation: | Department of Synthetic Chemistry, Kyoto University, Yoshida, Kyoto 606, Japan |
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| Abstract: | A structure and reactivity relationship has been determined on the reaction of isopropyl and n-butyl Grignard reagents and n-butyllithium with vinyl-(alkoxy)silanes and (amino)silanes. The addition to the vinyl group has been analyzed in terms of the nucleophile HOMO-vinyl group LUMO interaction. |
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