Synthesis of 2-substituted 1,3-butadienyl compounds by palladium-catalyzed regioselective 1,2-elimination reaction of methylvinylcarbinol acetates |
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| Authors: | Adriano Carpita Fabrizio Bonaccorsi Renzo Rossi |
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| Institution: | Istituto di Chimica Organica - Facoltà di Scienze MFN - Università via Risorgimento 35 - 56100 Pisa - Italy |
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| Abstract: | Alkylation of the dianion of 3-methyl-3-buten-2-ol, followed by acetylation and palladium-catalyzed 1,2-elimination reaction of the so obtained methylvinylcarbinol acetates allows to synthesize regioselectively 2-substituted 1,3-butadienyl compounds having high isomeric purity. |
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