Palladium-catalyzed [3 + 2] cycloaddition reaction using 2-(sulfonylmethyl)- or 2-(cyanomethyl)allyl carbonate |
| |
| Authors: | Isao Shimizu Yukihiro Ohashi Jiro Tsuji |
| |
| Institution: | Tokyo Institute of Technology, Meguro, Tokyo 152, Japan |
| |
| Abstract: | Reaction of ethyl 2-(sulfonylmethyl)- or 2-(cyanomethyl)allyl carbonate with α,β-unsaturated esters or ketones in the presence of PD2(dba)3·.CHCl3-dppe catalyst gave highly functionalized cyclopentanes regio-selectively in good yields. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
