Definitive evidence for a proximal effect of pyridine in the NaOCl/Mn(porphyrin)x / pyridine catalytic oxygenation system |
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Authors: | Olga Bortolini Michel Momenteau Bernard Meunier |
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Affiliation: | 1. Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31400 Toulouse, France;2. Institut Curie, Section Biologie, Bât. 112, Centre Universitaire, 91405 Orsay, France |
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Abstract: | Using pyridine-attached manganese porphyrins, it has been possible to obtain definitive evidence that pyridine behaves as a proximal ligand in the NaOCl/Mn(porphyrin)X catalytic oxygenation system. |
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