Stereoelectronic control in the base catalyzed hydrolysis of five-membered ring cyclic phosphonamidates |
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| Authors: | Ji-Charng Yang David G Gorenstein |
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| Institution: | Department of Chemistry, University of Illinois at Chicago Chicago, Illinois 60680 U.S.A. |
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| Abstract: | The base catalyzed hydrolysis of 2-phenyl-2-oxo-3-(2,6-dimethylphenyl)-1,3,2-oxazaphospholidine, , and 2-phenyl-2-oxo-3-(2,6-diisopropylphenyl)-1,3,2-oxazaphospholidine, , yields ring opened products involving 95% and 100% P-O cleavage, respectively. |
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