Reaction of alkenes and dienes with t-butylmagnesium halides and zirconocene dihalides. A convenient procedure for hydrozirconation and a novel t-butylzirconation of conjugated alkenes |
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| Authors: | Ei-ichi Negishi Joseph A Miller Tadao Yoshida |
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| Institution: | Department of Chemistry, Purdue University, W. Lafayette, Indiana 47907 U.S.A. |
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| Abstract: | The reaction of nonconjugated monosubstituted alkenes with t-BuMgCl and Cl2ZrCp2 at room temperature produces the corresponding monoalkylzirconium derivatives in high yields, while conjugated alkenes undergo either a novel t-butylzirconation or hydrozirconation depending on the reaction conditions. |
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