Synthese stereospecifique de l'ester methylique de l'acide amino-2 oxo-8 epoxy-9,10 decanoique (2s,9r) N - protege. |
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| Authors: | R Jacquier R Lazaro H Raniriseheno P Viallefont |
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| Institution: | Unite´associe´e au CNRS no 468, Place E. Bataillon 34060 Montpellier Cedex France. |
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| Abstract: | The first stereospecific synthesis of methyl (2S,9R) N-tBOC 2-amino 8-oxo 9,10-epoxydecanoate has been carried out by using two steps allowing a chirality control: a stereospecific alkylation of the Schiff base 4 and Sharpless epoxidation of the allylic alcohol 6. |
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