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Analytical enantiomer separation of aliphatic diols as boronates and acetals by complexation gas chromatography
Authors:V Schurig  D Wistuba
Institution:Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, D 7400 Tübingen, W. Germany
Abstract:Cyclic boronates and acetals of mono- and dialkylsubstituted 1,2-, 2,3- 1,3- & 1,4- diols have been quantitatively separated into enantiomers by complexation gas chromatography utilizing optically active metal chelates. An efficient, precise & sensitive method for determining enantiomeric purities for volatile glycols is thus available.
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