Stereoselective synthesis of vinylgermanes and their facile transformation into vinyl halides |
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| Authors: | Hiroji Oda Yoshitomi Morizawa Koichiro Oshima Hitosi Nozaki |
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| Institution: | Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Kyoto 606, Japan |
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| Abstract: | Whereas iododegermylation of (Z)-1-triethylgermyl-1-dodecene gives (Z)-1-iodo-1-dodecene, bromodegermylation proves to give (E)-1-bromo-1-dodecene. Two general procedures for the preparation of vinylgermanes are also described. |
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