Diastereoselective ireland-claisen rearrangement of allylic alcohols |
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Authors: | Jin K. Cha S.C. Lewis |
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Affiliation: | Department of Chemistry, Vanderbilt University Nashville, Tennessee 37235, USA |
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Abstract: | The “chelation-controlled” Ireland-Claisen rearrangement of allylic glycolate esters is described in which the stereocontrol of the prochiral sp2 sites is achieved by the allylic oxygen substitutent. |
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