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Synthetic approach to anthracyclinone C-glycosides |
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| Authors: | Edward M. Acton Kenneth J. Ryan Michael Tracy |
| Affiliation: | Bio-Organic Chemistry Laboratory, Sri International, Menlo Park, California 94025, U.S.A. |
| Abstract: | Stereospecific coupling of a pentadienyl chain to C.1 of daunosamine followed by Diels-Alder reactions with quinones gave a new synthesis of C-glycosides, including the first intermediates to anthracycline C-glycosyl isosteres. |
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