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A simple route to the 7H-cyclopenta[a]pentalene system: preparation of the 1,2,3,4,5,6-hexachloro-derivative.
Authors:Gordon I. Fray  Gillian M. Hearn  James C. Petts
Affiliation:School of Chemistry, The University, Bristol BS8 ITS, England
Abstract:Reaction of octachlorofulvene (3) with diazomethane leads to the formation of the tricyclic tetraene (4), which on dechlorination with tin(II) chloride gives 1,2,3,4,5,6-hexachloro-7H-cyclopenta[a]pentalene1 (2).
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