Metal catalyzed cross-coupling reactions of carbanions α to silafunctional groups. New α-hydroxyalkyl anion equivalents |
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| Authors: | Kohei Tamao Takahisa Iwahara Ryuichiro Kanatani Makoto Kumada |
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| Institution: | Department of Synthetic Chemistry, Kyoto University, Yoshida, Kyoto 606, Japan |
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| Abstract: | Carbanions α to (alkoxy)silyl or (amino)silyl groups act as nucleophilic α-hydroxy-alkylating agents for organic halides and epoxides via the metal catalyzed coupling reaction and the subsequent oxidative cleavage of the carbon-silicon bond. |
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