Selective oxidation of saturated hydrocarbons at secondary positions |
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Authors: | Derek H.R. Barton Jean Boivin Nubar Ozbalik Kathy M. Schwartzentruber |
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Affiliation: | Institut de Chimie des Substances Naturelles, C.N.R.S., 91190 Gif-sur-Yvette, France |
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Abstract: | The selectivity in the oxidation of saturated hydrocarbons by oxygen in pyridine-acetic acid in presence of an iron catalyst and zinc is strongly dependant on the oxygenation of the reaction mixture; using air and slow stirring, it is possible to attack adamantane and -1,4-dimethylcyclohexane almost exclusively at the secondary positions. |
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