Intramolecular acylation of α-sulfinyl carbanion a new general route to 5-methylene-2-cyclopentenones |
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| Authors: | Manat Pohmakotr Sirirat Chancharunee |
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| Institution: | Department of Chemistry, Faculty of Science, Mahidol University, Rama VI Road, Bangkok 10400, Thailand |
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| Abstract: | A convenient synthesis of 5-methylene-2-cyclopentenones including Methylenomycin B involving the intramolecular acylation of α-sulfinyl carbanion followed by methylation and pyrolysis is described. |
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