New synthesis of vinyl selenides nucleophilic substitutions of unactivated vinyl halides by selenide anions |
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| Authors: | M Tiecco L Testaferri M Tingoli D Chianelli M Montanucci |
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| Institution: | Istituto di Chimica Organica, Facoltà di Farmacia, Università di Perugia, Italy |
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| Abstract: | Alkyl and aryl selenide anions react with unactivated vinyl halides, in dipolar aprotic solvents, to give alkyl or aryl vinyl selenides in good yields. These reactions are stereospecific and occur with retention of configuration. |
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