Asymmetric synthesis of the putative structure of (-)-oryzoxymycin |
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| Authors: | Bunnage Mark E Ganesh Thota Masesane Ishmael B Orton Darren Steel Patrick G |
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| Institution: | Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, UK. |
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| Abstract: | reaction: see text] A short asymmetric synthesis of (2'S,5R,6R)-2'-6-amino-5-hydroxy-1,3-cyclohexadiene-1-carbonyloxy]propionic acid, the enantiomer of the reported structure of (+)-oryzoxymycin is described. The reported spectral data does not match that obtained for synthetic "oryzoxymycin". |
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