Efficient and general synthetic method for preparing oligoenynes with either trans- or cis-olefinic configuration |
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| Authors: | Takayama Yuuki Delas Christophe Muraoka Kenji Sato Fumie |
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| Institution: | Department of Biomolecular Engineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8501, Japan. |
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| Abstract: | reaction: see text] Efficient and practical synthesis of a variety of 1-iodo-4-trimethylsilylbut-1-en-3-yne derivatives with trans- and cis-olefinic configuration, and their repeated use as building blocks for the synthesis of trans- and cis-oligoenynes, respectively, are described. |
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