Reactions of 3-Nitro-1,2,4-Triazole Derivatives with Alkylating Agents. 2. Alkylation of a Neutral Heterocycle by Dimethyl Sulfate |
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| Authors: | G T Sukhanov G V Sakovich A G Sukhanova A Yu Lukin |
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| Institution: | (1) Institute of Problems of Chemical Energetic Technologies, Siberian Branch, Russian Academy of Sciences, 659322 Biisk, Russia;(2) Federal Research and Production Center “Altai”, 659322 Biisk, Russia |
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| Abstract: | The reaction of 3-nitro-1,2,4-triazole and 5-methyl-3-nitro-1,2,4-triazole with dimethyl sulfate leads to mixtures of N-mono-
and N,N-dimethylnitrotriazolium compounds and products of the subsequent conversion of the latter, namely, N,N-dimethyl-1,2,4-triazol-5-ones.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1168–1173, August, 2005. |
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| Keywords: | N-alkyl-3-nitro-1 2 4-triazole N N-dimethyl-1 2 4-triazol-5-one alkylation regioselectivity |
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