Application of Bis-Sulfonamides in Asymmetric Catalysis. Addition of Diethylzinc to Prochiral Aldehydes |
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| Authors: | Lake F Moberg C |
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| Institution: | (1) Department of Chemistry, Organic Chemistry, Royal Institute of Technology, SE 100 44 Stockholm, Sweden |
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| Abstract: | The review summarizes the authors' and published data on the Ti(OPr-i)4-catalyzed addition of diethylzinc to prochiral aldehydes in the presence of bis-sulfonamides. The effect of bis-sulfonamide structure and other factors on the enantioselectivity of formation of secondary alcohols is discussed. |
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