| 过渡金属核磁共振谱 |
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| 引用本文： | 陈振中. 过渡金属核磁共振谱[J]. 波谱学杂志, 1995, 12(5): 525-540 |
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| 作者姓名： | 陈振中 |
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| 作者单位： | 香港中文大学化学系, 香港沙田 |
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| 摘 要： | 以数种过渡金属的核磁共振研究介绍了有关技术在近年的发展;内容集中于如何从图谱取得化学信息。讨论分为固体谱与液体谱两部分,固体谱会着重谱线的分析,液体谱则集中对有关化学位移的理论解释。
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| 关 键 词： | 过渡金属 核磁共振 四极矩核 自旋1/2核 静态谱 魔角旋转谱 屏蔽张量 四极矩弛豫 相关时间 |
^^THE NMR SPECTROSCOPY OF TRANSIIION METALS |
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| Chen Zhenzhong and,Steve C F. Au-Yeung. ^^THE NMR SPECTROSCOPY OF TRANSIIION METALS[J]. Chinese Journal of Magnetic Resonance, 1995, 12(5): 525-540 |
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| Authors: | Chen Zhenzhong and Steve C F. Au-Yeung |
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| Affiliation: | Department of Chemistry, The Chinese University of Hong Kong, Shatin, N. T. Hong Kong |
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| Abstract: | his article reviews the recent devefopment of transition metal NMR spectroscopywith the main emphasis on the methodology for the extraction of chemicalinformation. The discussion is divided into two parts. Solid state NMR focusesmainly in the line shape analysis while the solution part concerns with theinterpretation of chemical shifts. |
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| Keywords: | Transition metal NMR Quabrupole nuclei Spin half nuclei Static spectra Magic angle spinning spectra. Shielding tensor Quadrupolar relaxation Correlation time |
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