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铜(Ⅱ)离子印迹聚合物的制备及性能
引用本文:朱建华,李欣,强亮生.铜(Ⅱ)离子印迹聚合物的制备及性能[J].高等学校化学学报,2006,27(10):1853-1855.
作者姓名:朱建华  李欣  强亮生
作者单位:哈尔滨工业大学应用化学系,哈尔滨,150090
摘    要:选择油酸为功能单体, 二乙烯基苯为交联剂, 应用乳液聚合方法制备了Cu(Ⅱ)离子印迹聚合物, 并对其性能和吸附机理进行了研究.

关 键 词:铜离子  印迹聚合物  制备  性能
文章编号:0251-0790(2006)10-1853-03
收稿时间:03 7 2006 12:00AM
修稿时间:2006-03-07

Preparation and Characterization of Cu(Ⅱ)-Molecularly Imprinted Polymer
ZHU Jian-Hua,LI Xin,QIANG Liang-Sheng.Preparation and Characterization of Cu(Ⅱ)-Molecularly Imprinted Polymer[J].Chemical Research In Chinese Universities,2006,27(10):1853-1855.
Authors:ZHU Jian-Hua  LI Xin  QIANG Liang-Sheng
Institution:Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150090, China
Abstract:Cu(Ⅱ)-Molecularly imprinted polymer was prepared by the emulsion polymerization approach by using oleic acid and divinylbenzene as the functional monomer and the cross-linker separately. The results show that the imprinted polymer adsorbed Cu(Ⅱ) in water with a high velocity and favorable selectivity through copper ion entering into its cavity and replacing hydrogen of hydroxyl group. Autosorb instrument was used to examine the properties and structure of the imprinted polymer. Many holes in surface of the Cu(Ⅱ)-molecule imprinted polymer which possess high availability are filled because of adsorption.
Keywords:Cu(Ⅱ) ion  Imprinted polymer  Preparation  Property
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