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Exploiting phenyl embraces and pi-stacking in the assembly of arrays of tetraphenylphosphonium p-sulfonatocalix[4]arene
Authors:Makha Mohamed  Raston Colin L  Sobolev Alexandre N  White Allan H
Institution:School of Biomedical and Chemical Sciences, University of Western Australia, Crawley, WA 6009, Australia.
Abstract:Phenyl embraces involving tetraphenylphosphonium cations feature in complexes of p-sulfonatocalix4]arene where a phenyl ring of a cation is included in the cavity of the calixarene. The overall structures are based on pseudo-polymorphic supramolecular arrays and their formation is templated or induced by lanthanide ions.
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