Tandem conjugate addition-elimination reaction promoted by chiral pyrrolidinyl sulfonamide (CPS) |
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| Authors: | Xu Junye Fu Xiao Low Ruijuan Goh Yong-Peng Jiang Zhiyong Tan Choon-Hong |
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| Affiliation: | Department of Chemistry, National University of Singapore, Singapore. |
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| Abstract: | Chiral pyrrolidinyl sulfonamides have been found to promote the conjugate addition-elimination reaction between activated allylic bromides and 1,3-dicarbonyl compounds with high enantioselectivities and the highly functionalised products can be used to generate a variety of interesting enantiomerically pure compounds via simple transformations. |
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