| 三价铜的化学 |
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| 引用本文： | 石铁生.三价铜的化学[J].河北大学学报(自然科学版),1988(4). |
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| 作者姓名： | 石铁生 |
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| 作者单位： | 河北大学化学系 |
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| 摘 要： | 通过70篇文献的考察对三价铜的发展在下列方面进行了论述:结构及各种存在形式;UV-VIS光谱及电极电位;三价铜做氧化剂在分析化学中的应用;氧化还原体系的反应动力学及机理,指出了某些问题应进一步研究,揭示了一些尚未开发的课题。
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The Chemistry of Ter-valent Copper |
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| Abstract: | The development of the chemistry of ter-valent copper was reviewed from a survey of the literature.It was discussed in the following aspects: The forms of Cu ( Ⅲ ); UV-VIS spectra and redox electrode potentials of Cu(Ⅲ); its application in analytical chemistry; kinetics and mechanisms of redox reactions. It was indicated that the existent forms and the equilibrium relationships of perio-dato and tellurato-Cu(Ⅲ) complexes in aqueous solution should be further investigated.It is worthwhile exploring the polymerization reactions of some monomer induced by this redox system.Understanding the details of the reactions of Cu(Ⅲ) nay be very important, because the copper is involved in many biological electron-transfer reactions. 70 related papers were provided to the discussion. |
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