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Anomalous effects in charging of Pd powders with high density hydrogen isotopes
Authors:Akira Kitamura  Takayoshi Nohmi  Akira Taniike  Reiko Seto
Affiliation:a Division of Marine Engineering, Graduate School of Maritime Sciences, Kobe University, 5-1-1 Fukaeminami-machi, Higashinada-ku, Kobe 6580022, Japan
b Technova Inc., 1-1-1 Uchisaiwai-cho, Chiyoda-ku, Tokyo 1000011, Japan
Abstract:A twin system for hydrogen absorption experiments has been constructed to replicate the phenomenon of heat and 4He generation by D2 gas absorption in nano-sized Pd powders reported by Arata and Zhang, and to investigate the underlying physics. For Pd⋅Zr oxide nano-powders, anomalously large energies of hydrogen isotope absorption, 2.4±0.2 eV/D-atom and 1.8±0.4 eV/H-atom, as well as large loading ratio of D/Pd=1.1±0.0 and H/Pd=1.1±0.3, respectively, were observed in the phase of deuteride/hydride formation. The sample charged with D2 also showed significantly positive output energy in the second phase after the deuteride formation.
Keywords:  mmlsi6"   onclick="  submitCitation('/science?_ob=MathURL&  _method=retrieve&  _eid=1-s2.0-S0375960109007877&  _mathId=si6.gif&  _pii=S0375960109007877&  _issn=03759601&  _acct=C000053510&  _version=1&  _userid=1524097&  md5=e996afc46ebf9be14f65178bfcf8fed8')"   style="  cursor:pointer  "   alt="  Click to view the MathML source"   title="  Click to view the MathML source"  >  formulatext"   title="  click to view the MathML source"  >Pd&sdot  Zr nano-powder   Deuterium absorption   Hydrogen absorption   D/Pd ratio   Isotope effect
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