Synthesis of a derivative of a pentasaccharide repeating unit of the O-antigenic polysaccharide of the bacterium Klebsiella pneumoniae O3 as a benzoylated 2-methoxycarbonylethyl thioglycoside |
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Authors: | Abronina P I Galkin K I Backinowsky L V Grachev A A |
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Institution: | (1) Istituto di Chimica Biomolecolare (ICB ), CNR, via Campi Flegrei 34, Comprensorio Olivetti, 80078 Pozzuoli, (Na), Italy;(2) Dipartimento di Biologia Animale ed Ecologia Marina, Sez. Ecologia Microbica e Biotecnologie, Univ. Messina, salita Sperone 31, 98166 Messina, Italy; |
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Abstract: | Block synthesis of a fully benzoylated derivative of the pentasaccharide α-d-Manp-(1→3)-α-d-Manp-(1→2)-α-d-Manp-(1→2)-α-d-Manp-(1→2)-α-d-Manp-SCH2CH2CO2Me, the glycoside of the repeating unit of the O-antigenic polysaccharide of the bacterium Klebsiella pneumoniae O3, was performed. |
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