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Synthesis and Structure of Mixed Distannoxane Dimers [ClR2SnOSnR2′Cl]2
引用本文:YanLUE LinHongWeng 等.Synthesis and Structure of Mixed Distannoxane Dimers [ClR2SnOSnR2′Cl]2[J].中国化学快报,2002,13(2):185-188.
作者姓名:YanLUE  LinHongWeng
作者单位:NationalKeyLaboratoryofElemento-OrganicChemistry,NankaiUniversity,Tianjin300071
摘    要:Mixed distannoxane dimers ClR2SnOSnR2′Cl]2 were synthesized by the reaction of R2SnO(R=Bu,Pr) and R2SnCl2(R=Me,Ph,Cy,Oct). The crystal structures of compound 1 and 5 show they are ladder-type dimers that contain a central planar Sn2O3 four-membered ring. Both endo-and exo-Sn atoms are five-coordinate.

关 键 词:合成  晶体结构  混合双环氯氧锡烷二聚物
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