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STUDY ON THE SYNTHESIS AND PROPERTIES OF POLY(ESTER-IMIDEETHER)MULTIBLOCK COPOLYMERS
Authors:Zu-yao Shan  Zhen-yi Li Institute of Chemistry  Chinese Academy of Sciences  Beijing  China
Institution:Zu-yao Shan,Zhen-yi Li Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China
Abstract:A new class of poly(ester-imide-ether) multiblock copolymers was synthesized by transes-terification and meltcopolymerization of dimethyl terephthalate (DMT) and N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide withethylene glycol (EG) and polytetramethylene glycol (PTMG). The structure of the above copolymers was characterized by~1H-NMR and IR spectroscopy. Some properties of the coplymers were also examined. It was found that their mechanicalproperties and heat stability, compared with poly(ether-ester) copolymers, were obviously improved.
Keywords:N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide  Polyester-polyether copolymer  Poly-(ester-imideether) multiblock copolymer  Imide modification
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