Polarization Fourier transform infrared spectroscopy on ionic single crystal surfaces: Davydov splittings, adsorbated structures and 2D-phase transitions on NaCl(100) and MgO(100) |
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Authors: | J Heidberg E Kampshoff M Kandel R Kühnemuth D Meine O Schönekäs M Suhren and H Weiss |
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Institution: | (1) Institut für Physikalische Chemie und Elektrochemie der Universität Hannover, Callinstrasse 3-3A, W-3000 Hannover, 1, Germany |
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Abstract: | Polarized infrared spectra of adsorbates on NaCl(100) and MgO(100) single crystal cleavage planes reveal Davydov splittings, structures with adsorbate orientations and/or 2D-phase transitions, in concert with diffraction studies. CO2 on NaCl shows the sharpest adsorbate spectra known (
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