Ruthenium-catalyzed cycloaddition of aryl azides and alkynes |
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Authors: | Rasmussen Lars Kyhn Boren Brant C Fokin Valery V |
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Institution: | Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA. |
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Abstract: | The formation of 1,5-disubstituted 1,2,3-triazoles from aryl azides and alkynes was readily accomplished using Cp*RuCl]4 catalyst in dimethylformamide. It was also demonstrated that the reaction provided higher yields, cleaner product, and shorter reaction times when carried out under microwave irradiation. |
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