Theoretical study of the conformational features of triosmium clusters |
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| Authors: | V. A. Potemkin N. N. Ivshina V. A. Maksakov |
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| Affiliation: | 1.Chelyabinsk State University,Chelyabinsk,Russia;2.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division,Russian Academy of Sciences,Novosibirsk,Russia;3.I. Ya. Postovskii Institute of Organic Synthesis, Ural Division,Russian Academy of Sciences,Ekaterinburg,Russia |
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| Abstract: | The article summarizes the results of the study of conformational states of triosmium clusters with organic ligands. Special attention is paid to the structural features of molecular carbonyl cluster complexes with M n (CO) m L organic ligands. The effect of the structure surface charge, solvent, cluster crystalline state, and intermolecular and intramolecular interactions on the cluster conformational state is also determined. |
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