Experimental and theoretical evidence for U(C6H6) and Th(C6H6) complexes |
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| Authors: | Infante Ivan Raab Juraj Lyon Jonathan T Liang Binyong Andrews Lester Gagliardi Laura |
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| Affiliation: | Department of Physical Chemistry, University of Geneva, 30 Quai Ernest Ansermet, CH-1211, Geneva, Switzerland. |
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| Abstract: | The vibrational spectra of UBz and ThBz have been measured in solid argon. Complementary quantum chemical calculations have allowed the assignments of the vibrational spectra. According to the calculations, AcBz are stable molecules, as well as other species like BzAcBz and BzAc2Bz. Experimentally, there is no evidence for the sandwich compounds BzAcBz and BzAc2Bz due to the limitations in the reagent concentrations. |
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