| 摘 要： | A new metal-organic coordination polymer [Pb(mfpdc)(CH3OH)]n (1, mfpdc=2,6-dimethyl-4-(2-furanyl) pyridine-3,5-dicarboxylate) was synthesized and characterized by single-crystal X-ray analyses. The crystal is orthorhombic, space group Pbca, a=15.6297(18), b=9.4803(11), c=18.598(2), V=2755.8(6)3 , Z=8, Mr=498.44, Dc=2.403 Mg/m3 , F(000)=1872, the final R=0.0275 and wR=0.0726 (I>2 (I)). There are interesting polynuclear zigzag (PbO5 ) n chains in the structure of 1, and there have interesting axially chiral S-and R-unit Pb4L units constructed from prochiral organic ligands through C-H···O bonding. The (R/S)-Pb4L units by sharing Pb centers generate a 2-D coordination network, in which there exist rare π65 ···Pb(3.2610 ) interactions. The solid-state photoluminescent emission of compound 1 appears at 487 nm.
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