| Synthesis, Structure and Characterization of a New Iron Coordination Polymer： [Fe（L）（trans-l,4-chdc）]n |
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| 作者姓名： | WANG Xiu-Yan ZHANG Yan-Na LI Dan |
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| 作者单位： | [1]Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China [2]College of Chemistry, Jilin Normal University, Siping 136000, China |
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| 基金项目： | Supported by the Institute Foundation of Siping Ci17 （No. 2009011） |
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| 摘 要： | A novel Fe(Ⅱ) coordination polymer Fe(L)(trans-1,4-chdc)]n has been hydrothermally synthesized by using 1,4-cyclohexanedicarboxylic acid (1,4-H 2 chdc) and 2-(2-fluorophenyl)-1H-imidazo4,5-f]1,10]phenanthroline (L). Crystallographic data: monoclinic, space group C2/c with a=14.571(5), b=32.389(6), c=10.948(5) , β=115.186(5)°, V=4676(3)3 , Z=8, C27H21FFeN4O4 , Mr=540.33, Dc=1.535 g/cm3 , F(000)=2224, μ(MoKa)=0.697 mm-1 , R=0.0462 and wR =0.1110. The two kinds of trans-1,4-chdc ligands link neighboring Fe(Ⅱ) atoms to yield a two-dimensional layer structure. The π-π interactions between the L ligands of neighboring layers result in a three-dimensional supramolecular architecture. The IR and UV-vis spectra of the compound have been investigated in detail.
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| 关 键 词： | coordination polymer crystal structure 2-(2-fluorophenyl)-1H-imidazo[4 5-f][1 10]phenanthroline 1 4-cyclohexanedicarboxylic acid |
Synthesis, Structure and Characterization of a New Iron Coordination Polymer: [Fe(L)(trans-l,4-chdc)]n |
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| WANG Xiu-Yan,ZHANG Yan-Na,LI Dan.Synthesis, Structure and Characterization of a New Iron Coordination Polymer: [Fe(L)(trans-l,4-chdc)]n[J].Chinese Journal of Structural Chemistry,2012,31(11):1589-1593. |
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| Authors: | WANG Xiu-Yan a b ZHANG Yan-Na a b LI Dan |
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| Institution: | Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China College of Chemistry, Jilin Normal University, Siping 136000, China |
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| Abstract: | |
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| Keywords: | coordination polymer crystal structure 2-(2-fluorophenyl)-lH-imidazo[4 5-f] [1 10]phenanthroline 1 4-cyclohexanedicarboxylie acid |
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