Thermoregulated Liquid/Liquid Biphasic Catalysis and Its Application |
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| Authors: | Yanhua Wang Jingyang Jiang Zilin Jin |
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| Institution: | (1) Research Group on Homogeneous Catalysis of the Hungarian Academy of Sciences at the Institute of Physical Chemistry, Lajos Kossuth University, P.O. Box 7, H-4010 Debrecen, Hungary;(2) Institute of Physical Chemistry, Lajos Kossuth University, P.O. Box 7, H-4010 Debrecen, Hungary |
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| Abstract: | A brief overview of our recent research results of thermoregulated liquid/liquid biphasic catalysis is presented. Emphasis is given to the general principles of thermoregulated phase-transfer catalysis (TRPTC) and thermoregulated phase-separable catalysis (TPSC). In addition, the applications of TRPTC and TPSC in biphasic catalysis are also discussed. The introduction of TRPTC to biphasic system is free from the shortcomings of classical aqueous/organic two-phase catalysis, in which the application scope is restrained by the water solubility of the substrate. Meanwhile, TPSC provides a very simple and reliable way to deal with the separation of catalyst in homogeneous catalysis. The common advantages of TRPTC and TPSC are characterized by homogeneous catalysis coupled with convenient biphasic separation. |
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| Keywords: | thermoregulated ligands thermoregulated phase-transfer catalysis thermoregulated phase-separable catalysis hydroformylation hydrogenation |
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