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Silver-catalyzed imination of sulfoxides and sulfides
Authors:Cho Gae Young  Bolm Carsten
Institution:Institute of Organic Chemistry, RWTH Aachen University, Germany.
Abstract:reaction: see text] Silver salts in the presence of a chelating ligand efficiently catalyze the stereospecific imination of sulfoxides and sulfides with sulfonylamides and PhI(OAc)(2) to afford sulfoximines and sulfilimines, respectively, in good yields.
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